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Discontinuously Reinforced
Aluminum-based Composites (DRACs) are listed among the most
promising structural materials owing to their lightweight and improved
mechanical properties including wear resistance. The DRACs manufactured by
traditional solidification and powder metallurgy methods so far, however,
are still not profitable, in comparison with the widely used structural
steel parts. In traditional techniques, expensive reinforcing particles
manufactured separately are used. The objective of this project is to
develop an in-situ molten metal technique, through which the reinforcing
particulates such as SiC and AlN are formed in-situ in the aluminum alloy
matrix with low cost and improved reinforcing properties.
To develop this novel technique, thermodynamic properties of the
reinforcements in Al alloy matrix, and the influence of process variables
on the formation of equilibrium reinforcing particulates were modeled
using Gibbs energy minimization method. It is found that the thermodynamic
stability of SiC in Al-alloy matrix is affected by the compositions of the
alloy matrix and temperature. AlN is thermodynamically stable in Al-Si
alloy over the whole range of processing and application temperatures.
Experimental studies showed that the novel molten metal technique is
technologically feasible. The reinforcing particulates formed in-situ were
small in size and were uniformly dispersed in the alloy matrix. It was
also found that the formation of reinforcing particulates was influenced
by the composition of alloy matrix, temperature, N2 gas bubble
size, and the oxygen content in the bubbling gas.
The work in progress includes the development of a kinetic model to
understand the process mechanism, investigation of the microstructure and
properties of the DRACs, and optimization of the materials and process
parameters.
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